The tune is taken from 'Words,' Evans' first release as an independent artist after seven studio albums for RCA.
The performance and interview was filmed on location during the AT&T Block Party at the 2017 NCAA March Madness Music Festival.
Last October, the group – Naomi Cooke, Hannah Mulholland and Jennifer Wayne – made their debut at the Grand Ole Opry and performed backstage in the Opry Lounge.
The official video captures the fans – and Bentley – in all their beer-drinking, festive glory.
The multi-instrumentalist glides through several performance scenes showcasing signature textured vocals in a rustic Nashville, TN warehouse.
'For The First Time' is the follow-up to his most recent No. 1 single, 'If I Told You,' the first off his long-awaited as-yet-untitled fifth Capitol Records Nashville album.
The country music icon took to Instagram to post a short video revealing the 16 songs that make up her new LP, 'Now,' set to be released September 29.
"Legends" is the first single off Ballerini's forthcoming as-yet-untitled second album.